90292-34-5

Upstream product

• 19430-93-4 3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexene 
• 108-98-5 thiophenol 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 125556-56-1 ((E)-3,4,4,5,5,6,6,6-Octafluoro-hex-2-ene-1-sulfinyl)-benzene 
• 125556-62-9 2-((Z)-3,4,4,5,5,6,6,6-Octafluoro-1-phenylsulfanyl-hex-2-enyl)-cyclohexanone 
• 125556-65-2 (Z)-5,6,6,7,7,8,8,8-Octafluoro-2-methyl-1-phenyl-3-phenylsulfanyl-oct-4-en-1-one 
• 125556-67-4 (Z)-5,6,6,7,7,8,8,8-Octafluoro-2-methyl-3-phenylsulfanyl-oct-4-enoic acid methyl ester 
• 125556-60-7 (Z)-10,11,11,12,12,13,13,13-Octafluoro-8-phenylsulfanyl-tridec-9-en-6-one 
• 125556-64-1 (Z)-5,6,6,7,7,8,8,8-Octafluoro-1-phenyl-3-phenylsulfanyl-oct-4-en-1-one 
• 125556-61-8 (Z)-7,8,8,9,9,10,10,10-Octafluoro-4-methyl-5-phenylsulfanyl-dec-6-en-3-one 
• 125556-66-3 (Z)-2-Ethyl-5,6,6,7,7,8,8,8-octafluoro-3-phenylsulfanyl-oct-4-enal 
• 125556-71-0 (2E,4Z)-6,6,7,7,8,8,8-Heptafluoro-1-phenyl-5-phenylsulfanyl-octa-2,4-dien-1-one 
• 125667-81-4 (Z)-5,6,6,7,7,8,8,8-Octafluoro-2-methyl-3-phenylsulfanyl-oct-4-enal 
• 125556-58-3 (Z)-6,7,7,8,8,9,9,9-Octafluoro-4-phenylsulfanyl-non-5-en-2-one 
• 125556-73-2 (2E,4Z)-2-Ethyl-6,6,7,7,8,8,8-heptafluoro-5-phenylsulfanyl-octa-2,4-dienal 
• 125556-72-1 (3E,5Z)-7,7,8,8,9,9,9-Heptafluoro-6-phenylsulfanyl-nona-3,5-dien-2-one 

Relevant academic research and scientific papers

Generation of F-Alkyl-substituted Vinyl Thionium Ion Intermediates and Their Reation with Silyl Enol Ethers. A New Route of δ-F-Alkyl-α,β:γ,δ-unsaturated Carbonyl Compounds

Treatment of 3-F-alkyl-3-fluoro-2-propenyl phenyl or ethyl sulfoxide with trimethylsilyl triflate and a hindered amine produces the corresponding vinyl thionium ion species, which readily reacts with silyl enol ethers to give δ-F-alkylated γ,δ-unsaturated

REACTION OF PERFLUOROALKYLETHYLENS WITH NUCLEOPHILES

Perfluoroalkylethylenes react with some carbon-, oxygen-, sulfur-, selenium-, nitrogen-, and phosphorus-based nucleophiles by formal SN2' displacement of fluoride ion.