1256452-00-2

Basic information

• Product Name: C₂₂H₄₀OSi₂
• Synonyms: C₂₂H₄₀OSi₂
• CAS NO: 1256452-00-2
• Molecular Weight: 376.73
• Mol File: 1256452-00-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₂H₄₀OSi₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₄₀OSi₂(1256452-00-2)
• EPA Substance Registry System: C₂₂H₄₀OSi₂(1256452-00-2)

Safety Data

• Hazardous Substances Data: 1256452-00-2(Hazardous Substances Data)

Upstream product

• 42478-47-7 (E)-1-(triethylsilyl)-1-propen-3-ol 
• 2652-46-2 3-(triethylsilyl)prop-2-yn-1-ol 
• 1256451-72-5 C₁₅H₃₄OSi₂ 
• 100-39-0 benzyl bromide 

Relevant articles and documents

Efficient approach to 3,3-bissilyl carbonyl and enol derivatives via retro-[1,4] brook rearrangement of 3-silyl allyloxysilanes

A facile and highly stereoselective retro-[1,4] Brook rearrangement of 3-silyl allyloxysilanes has been discovered. While basic hydrolysis of the formed (Z)-3,3-bissilyl lithium enolates provides 3,3-bissilyl carbonyl compounds efficiently, trapping the species with various electrophiles including alkyl halides leads to the exclusive O-substituted (Z)-3,3-bissilyl enol derivatives that can undergo a Sakurai reaction with aldehyde to produce the synthetically useful 1,2-diol diastereoselectively.