SYNTHESIS OF CARBON BRIDGED C-DISACCHARIDES

DOI: 10.1016/S0040-4039(00)99257-8

Source and publish data:

Tetrahedron Letters p. 3409 - 3412 (1989)

Update date:2022-08-03

Topics:

Authors:

Schmidt, Richard R.

Preuss, Rainer

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Article abstract of DOI:10.1016/S0040-4039(00)99257-8

Direct lithiation of the readily available 2-phenylsulfinyl-D-glucal 2 provides the 1-C-lithiated species 2A furnishing with 4-deoxy-4-formyl-D-glucose derivative 7 in a diastereocontrolled reaction the C-disaccharide intermediate 8.This compound is trans

Full text of DOI:10.1016/S0040-4039(00)99257-8

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