125783-04-2Relevant articles and documents
Trisubstituted Olefins via Ester-Derived (Silyloxy)acetylenes: A Highly Stereoselective Alternative to the Horner-Wadsworth-Emmons Reaction
Kowalski, Conrad J.,Sakdarat, Santi
, p. 1977 - 1979 (1990)
Crude ((triisopropylsilyl)oxy)acetylenes 2, prepared in one step from common esters 1, react with aldehydes in 60-65 percent overall yield after methanol quench to afford α,β-unsaturated esters 3 with very high E/Z stereoselectivity.