
Journal of Organic Chemistry p. 1977 - 1979 (1990)
Update date:2022-07-29
Topics:
Kowalski, Conrad J.
Sakdarat, Santi
Crude ((triisopropylsilyl)oxy)acetylenes 2, prepared in one step from common esters 1, react with aldehydes in 60-65 percent overall yield after methanol quench to afford α,β-unsaturated esters 3 with very high E/Z stereoselectivity.
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