1258865-75-6Relevant academic research and scientific papers
Controlled Generation of 3-Triflyloxyarynes
Uchida, Keisuke,Yoshida, Suguru,Hosoya, Takamitsu
supporting information, p. 4099 - 4109 (2016/11/26)
The efficient generation of 3-triflyloxyarynes, including those bearing a transformable group, through an iodine-magnesium exchange reaction of 1,3-bis(triflyloxy)-2-iodoarenes was achieved by using finely tuned reaction conditions that efficiently suppre
Synthesis and structural analysis of a novel iodinated cyclopentadienone via ring-contraction iodination and its application in synthesis of alkyne-functionalized cyclopentadienones
Chen, Xue-Yi,Barnes, Charles,Bai, Xinyan,Sandreczki,Peng, Zhonghua,Kadnikova, Ekaterina N.,Dias
supporting information; experimental part, p. 8171 - 8173 (2010/12/19)
The first iodinated cyclopentadienone was isolated and its structure was confirmed by single crystal X-ray analysis. Based on this intermediate, the first direct C-C bond formation on cyclopentadienone ring was achieved. The photo induced intramolecular charge transfer of alkynylated cyclopentadienones was evaluated by solvent polarity effect on their electronic absorption spectra.
