1259-34-3Relevant articles and documents
Oxidative perfluoroorganylation methods in group 12-16 chemistry: The reactions of haloperfluoroorganics and In and InBr, a convenient new route to AgRf (Rf = CF3, C6F5) and reactions of AgRf
Tyrra
, p. 149 - 152 (2001)
Perfluoroiodo organics RfI (Rf = n-CnF2n+1 (n = 1, 2, 3, 4, 6), i-C3F7, C6F5) and C6F5Br react with elemental indium in polyethers or THF to give
Catalysis with Pnictogen, Chalcogen, and Halogen Bonds
Benz, Sebastian,Poblador-Bahamonde, Amalia I.,Low-Ders, Nicolas,Matile, Stefan
supporting information, p. 5408 - 5412 (2018/03/23)
Halogen- and chalcogen-based σ-hole interactions have recently received increased interest in non-covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and mon
Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements
Deacon,Parrott
, p. 287 - 295 (2008/10/08)
Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.