1259-34-3

Usage

Chemical Description

Tris(pentafluorophenyl)arsine has a single arsenic atom with three pentafluorophenyl groups attached.

Upstream product

• 1735-62-2 Bromo-bis-(pentafluorphenyl)-thallium(III) 
• 34422-57-6 tris(pentafluorophenyl)bismuth 
• 18005-76-0 tris(pentafluorophenyl) arsenic(V) dichloride 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 344-04-7 bromopentafluorobenzene 
• 1206-46-8 trimethyl(pentafluorophenyl)silane 
• 7784-34-1 arsenic trichloride 
• 30123-12-7 silver(I)pentafluorobenzene 

Downstream Products

• 675120-59-9 C₁₈AsF₁₅IN₃ 
• 62452-84-0 bis{bis(trifluoromethyl)aminooxy}-tris(pentafluorophenyl)arsine 
• 319439-13-9 (p-fluorophenyl)(pentafluorophenyl)iodonium tetrafluoroborate 
• 66886-46-2 (C₆F₅)3AsClOCOCH₃ 
• 66886-50-8 (C₆F₅)3AsClOC₆H₅ 
• 14243-66-4 (triphenylphosphine) gold(III) trichloride 
• 66886-48-4 (C₆F₅)3AsClOCH₃ 
• 66886-49-5 (C₆F₅)3AsClOC₂H₅ 
• 66954-03-8 {Ag(As(C₆F₅)3)2}⁽¹⁺⁾*ClO₄^(1-)=Ag{As(C₆F₅)3}2ClO₄ 
• 18005-76-0 tris(pentafluorophenyl) arsenic(V) dichloride 
• 7440-02-0 nickel 
• 675120-68-0 1-phenyl-4-[tris(pentafluorophenyl)arsenic] iodo tetrazole-5-thione 
• 17841-89-3 tetrakis(pentafluorophenyl)diarsenic(III) oxide 

Relevant academic research and scientific papers

Oxidative perfluoroorganylation methods in group 12-16 chemistry: The reactions of haloperfluoroorganics and In and InBr, a convenient new route to AgRf (Rf = CF3, C6F5) and reactions of AgRf

Perfluoroiodo organics RfI (Rf = n-CnF2n+1 (n = 1, 2, 3, 4, 6), i-C3F7, C6F5) and C6F5Br react with elemental indium in polyethers or THF to give

Tertiary arsine ligands for the Stille coupling reaction

The Stille coupling reaction is one of the most important coupling reactions. It is well known that the triphenylarsine ligand can accelerate the reaction rate of Stille coupling. However, other arsine ligands have never been investigated for the Stille c

Catalysis with Pnictogen, Chalcogen, and Halogen Bonds

Halogen- and chalcogen-based σ-hole interactions have recently received increased interest in non-covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and mon

A first methodical approach to salts with unsymmetrical fluorophenyl(pentafluorophenyl)difluoroiodonium(V) cations [Rf(R F)IF2]+ (Rf=x-FC6H 4, x=2, 3, 4; RF=C6F5)

A promising approach to the unknown type of [Ar′(Ar)IF2]X salts is offered. x-FC6H4IF4 (x=2, 3, 4) reacts with C6F5BF2 in CH2Cl2 and forms [x-FC6H4(C6F5)IF 2][BF4] salts in good yields. For [4-FC6H 4(C6F5)IF2][BF4] the fluoro-oxidizer property is shown in reactions with weakly reducing agents like E(C6F5)3 (E=P, As, Sb, Bi) and ArI (Ar=4-FC6H4, C6F5). The fluorine/aryl substitution method is also applied to the synthesis of [(4-FC6H4)2IF2][BF4], an example with two identical aryl groups in the difluoroiodonium(V) moiety.

Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements

Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.