34422-57-6

Usage

Uses

Used in Organic Synthesis:
Tris(pentafluorophenyl)bismuth is utilized as a catalyst to facilitate a range of chemical reactions in organic synthesis. Its effectiveness in promoting transformations such as carbon-carbon bond formation, reduction reactions, and asymmetric catalysis makes it a valuable reagent in the synthesis of complex organic molecules.
Used in Material Development:
tris(pentafluorophenyl)bismuth has been studied for its potential in the development of new materials, leveraging its unique properties and reactivity to create innovative substances with specific applications.
Used in Medical Imaging:
Tris(pentafluorophenyl)bismuth has been explored as a contrast agent in medical imaging. Its properties may contribute to enhancing the visualization of internal structures during diagnostic procedures, potentially improving the accuracy and effectiveness of medical imaging techniques.

Upstream product

• 7787-58-8 bismuth(III) bromide 
• 74-96-4 ethyl bromide 
• 344-04-7 bromopentafluorobenzene 
• 7787-60-2 bismuth(III) chloride 
• 7439-95-4 magnesium 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 7440-69-9 bismuth 
• 30123-12-7 silver(I)pentafluorobenzene 

Downstream Products

• 3512-11-6 perfluoro(4-phenylpyridine) 
• 101565-24-6 perfluoro-2-methyl-3-phenyl-2-pentene 
• 196407-05-3 Bi(C₆F₅)3Cl₂ 
• 7440-69-9 bismuth 
• 363-72-4 Pentafluorobenzene 
• 434-90-2 decafluorobiphenyl 
• 1259-34-3 tris(pentafluorophenyl)arsine 
• 973-17-1 bis(pentafluorophenyl)mercury(II) 
• 31569-56-9 tris-(pentafluoro phenyl) indane 
• 1065-49-2 perfluoro(tetraphenyl)tin 
• 1043-50-1 pentafluorophenyl sulfide 
• 7787-61-3 bismuth(III) fluoride 
• 118798-75-7 tris(pentafluorophenyl)bismuth difluoride 
• 118798-75-7 tris(pentafluorophenyl)bismuthdifluoride 

Relevant academic research and scientific papers

The preparations and properties of tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf=CF3, C2F5, n-C3F7, n-C4F9, n-C6F13, n-C8H17, C6F5)

Tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf=CF3, C2F5, n-C3F7, n-C4F9, n-C6H13, n-C8H17, C6F5) are easily prepared in high yields from the reactions of perfluoroorganocadmium complexes with BiCl3 or BiBr3 in aprotic solvents.T

[(C6F5)2if2][BF4], the first salt with the electrophilic cation [(C6F5) 2if2]+: Synthesis, reactivity, and structure

The substitution of hypervalently bonded fluorine atoms in C 6F5IF4 was performed with C6F 5BF2 and resulted in the new salt [(C6F 5)2IF2][BF4]. The iodonium(V) salt was characterized by multi-NMR and Raman spectroscopy and X-ray crystal structure analysis. The fluorinating ability of the new electrophilic cation [(C6F5)2IF2]+ was exemplified in reactions with monovalent iodine compounds (C6F 5I, p-FC6H4I, and I2) and with electron-poor tri(organyl)pnictanes ER3 (E = P, As, Sb, Bi; R = C6F5). In a heterogeneous reaction with CsF in MeCN the [(C6F5)2IF2]+ cation forms the dinuclear [{(C6F5)2IF 2}2F]+ cation.

Silver compounds in synthetic chemistry. 1. A facile preparative route for pentafluorophenylsilver, AgC6F5 and its use as an oxidative pentafluorophenyl group transfer reagent in reactions with group 12 to 16 elements

AgC6F5 is directly and quantitatively formed from room temperature reactions of AgF and Me3SiC6F5 in N-donor solvents, particularly EtCN. Solutions of AgC6F5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the corresponding pentafluorophenyl element compounds in moderate to excellent yields. AgC6F5·EtCN crystallises with monoclinic symmetry (C2/c, Z = 8, a = 2301.4(5)pm, b = 1078.8(4)pm, c = 948.0(2)pm, β = 113.19(1)°) and exhibits chains of silver atoms with bridging C6F5 groups.

Pentafluorophenyliodine(V) Compounds. 2. Pentafluorophenyliodine Tetrafluoride C6F5IF4: Synthesis via Fluorine-Aryl-Subsitution on IF5 - Properties and Structure

The nucleophilic fluorine-aryl substitution reaction on IF5 with pentafluorophenyl, Bi(C6F5)3, leads to C6F5IF4 in good yields and high purity. The thermal stability of C6F5IF4 and its NMR spectrometric behaviour in solution will be discussed in comparison to IF5. In addition data of themolecular and crystal structure of the monovalent iodine parent compoun d C5F5I will be given.

Structures of Pentaarylbismuth Compounds

Pentaarylbismuth compounds were synthesized by the known reaction Ar3BiX2 + 2 Ar'Li ---> 2 LiX + BiAr3Ar'2.Whenever possible they were characterized by single-crystal X-ray structure determination.In two cases almost ideal square-pyramidal geometry was found, in a third case there were two different molecules in the unit cell, both again with square-pyramidal geometry.None of these novel bismuth pentaaryls exhibit the deep coloration and the dichroism of Bi(C6H5)5. - Key Words: Bismuth organic compounds / Fluorinated aromatic rings / Square pyramidal bismuth

Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements

Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.