1259026-15-7

Basic information

• Product Name: (E)-1-(4’,4’,5’,5’-tetramethyl)-1’,3’,2’-dioxaboronalyl-2-(2’’-naphtalen-1’’-yl)ethane
• Synonyms: (E)-1-(4’,4’,5’,5’-tetramethyl)-1’,3’,2’-dioxaboronalyl-2-(2’’-naphtalen-1’’-yl)ethane
• CAS NO: 1259026-15-7
• Molecular Weight: 280.175
• Mol File: 1259026-15-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(4’,4’,5’,5’-tetramethyl)-1’,3’,2’-dioxaboronalyl-2-(2’’-naphtalen-1’’-yl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(4’,4’,5’,5’-tetramethyl)-1’,3’,2’-dioxaboronalyl-2-(2’’-naphtalen-1’’-yl)ethane(1259026-15-7)
• EPA Substance Registry System: (E)-1-(4’,4’,5’,5’-tetramethyl)-1’,3’,2’-dioxaboronalyl-2-(2’’-naphtalen-1’’-yl)ethane(1259026-15-7)

Safety Data

• Hazardous Substances Data: 1259026-15-7(Hazardous Substances Data)

Downstream Products

• 1374000-00-6 (1R,4R,5R)-1,4,5-trihydroxy-3-((E)-2-(naphth-2-yl)vinyl)cyclohex-2-ene-1-carboxylic acid 
• 1374000-02-8 (1R,4R,5R)-1,4,5-trihydroxy-3-(2-(naphth-2-yl)ethyl)cyclohex-2-ene-1-carboxylic acid 
• 1374000-04-0 (1R,4R,5R)-1,4,5-trihydroxy-3-(2-(5,6,7,8-tetrahydronaphth-2-yl)ethyl)cyclohex-2-ene-1-carboxylic acid 

Relevant articles and documents

Direct Synthesis of Alkenylboronates from Alkenes and Pinacol Diboron via Copper Catalysis

We report an efficient approach for the direct synthesis of alkenylboronates using copper catalysis. The Cu/TEMPO catalyst system (where TEMPO = (2,2,6,6-tetramethylpiperidin-1-yl)oxyl) exhibits both excellent reactivity and selectivity for the synthesis of alkenylboronates, starting from inexpensive and abundant alkenes and pinacol diboron. This approach allows for the direct functionalization of both aromatic and aliphatic terminal alkenes. Mechanistic experiments suggest that the alkenylboronates arise from oxyboration intermediates.