1259394-39-2Relevant academic research and scientific papers
Asymmetric Synthesis of Enantiopure Pyrrolidines by C(sp3)?H Amination of Hydrocarbons
Darses, Benjamin,Dauban, Philippe,Lazib, Yanis,Retailleau, Pascal,Saget, Tanguy
supporting information, p. 21708 - 21712 (2021/08/30)
The asymmetric synthesis of enantiopure pyrrolidines is reported via a streamlined strategy relying on two sequential C?H functionalizations of simple hydrocarbons. The first step is a regio- and stereoselective catalytic nitrene C?H insertion. Then, a su
Asymmetric Synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes
Darses, Benjamin,Jarvis, Amandag.,Mafroud, Abdel-Kader,Estenne-Bouhtou, Genevieve,Dargazanli, Gihad,Dauban, Philippe
, p. 2079 - 2087 (2013/08/23)
An efficient asymmetric C-H amination of benzylic and allylic substrates, as well as of adamantane derivatives, through catalytic C-H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium(II) complex, an iodine(III) oxidant, an
