80859-83-2

Basic information

• Product Name: 1-benzene
• Synonyms: 1-benzene
• CAS NO: 80859-83-2
• Molecular Weight: 562.488
• Mol File: 80859-83-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzene(80859-83-2)
• EPA Substance Registry System: 1-benzene(80859-83-2)

Safety Data

• Hazardous Substances Data: 80859-83-2(Hazardous Substances Data)

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 828-51-3 1-Adamantanecarboxylic acid 

Downstream Products

• 113273-51-1 2-(1-adamantyl)ethyl phenyl sulfoxide 
• 126002-57-1 (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane 
• 137170-74-2 trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene 
• 88459-01-2 (1s,3s)-adamantan-1-yl(phenyl)sulfide 
• 75480-69-2 1-(phenylseleno)tricyclo<3.3.1.1^3,7>decane 

Relevant articles and documents

A benzene-bridged divanadium complex-early transition metal catalyst for alkene alkylarylation with PhI(O2CR)2viadecarboxylation

The synthesis, structure and catalytic activity of a benzene-bridged divanadium complex were comprehensively studied. The reduction of (Nacnac)VCl2(1) (Nacnac = (2,6-iPr2C6H3NCMe)2HC) supported by β-diketiminate with potassium graphite (KC8) by employing benzene as the solvent allows access to the benzene-bridged inverted-sandwich divanadium complex (μ-η6:η6-C6H6)[V(Nacnac)]2(2a), which can catalyze alkene alkylarylation with hypervalent iodine(iii) reagents (HIRs)viadecarboxylation to generate regioselectively diverse indolinones. Furthermore, the mild nature of this reaction was amenable to a wide range of functionalities on alkenes and HIRs. Mechanistic studies revealed a relay sequence of decarboxylative radical alkylation/radical arylation/oxidative re-aromatization.

Reactivity of arenes in substitution and additiopn reactions

The reactivity of arenes with 4-methylquinoline (substitution) as a typical heteroaromatic base and phenyl vinyl sulfone (addition) as a typical activated olefin has been studied under thermal and irradiation conditions.The results suggest that electron-withdrawing groups on the aromatic ring in arenes are detrimental to reactions.The crystal structures of arenes 10 and 1e are reported.