1260083-80-4

Upstream product

• 1304119-53-6 C₂₁H₂₁NO₅ 
• 75-16-1 methylmagnesium bromide 
• 13321-74-9 1-bromo-2,5-dimethoxy-4-methylbenzene 
• 133940-76-8 (4R)-3-acryloyl-4-phenyl-1,3-oxazolidin-2-one 
• 1329428-58-1 (R,E)-3-[3-(2,5-dimethoxy-4-methylphenyl)acryloyl]-4-phenyloxazolidin-2-one 

Downstream Products

• 528606-20-4 (R)-3-(2,5-dimethoxy-4-methylphenyl)butanoic acid 
• 1313051-72-7 (R)-3-(2,5-dimethoxy-4-methylphenyl)butanoic acid 
• 1329428-62-7 (R)-1,4-dimethoxy-2-(5-methoxypent-4-en-2-yl)-5-methylbenzene 
• 1329428-63-8 (R)-4-(2,5-dimethoxy-4-methylphenyl)pentanal 
• 1329428-64-9 (3S,6R)-6-(2,5-dimethoxy-4-methylphenyl)-2-methylheptane-2,3-diol 
• 1329428-66-1 2-[(2R,5S)-5,6-dihydroxy-6-methylheptan-2-yl]-5-methylcyclohexa-2,5-diene-1,4-dione 
• 1329428-67-2 (3R,6R)-6-(2,5-dimethoxy-4-methylphenyl)-2-methylheptane-2,3-diol 
• 1329428-68-3 2-[(2R,5R)-5,6-dihydroxy-6-methylheptan-2-yl]-5-methylcyclohexa-2,5-diene-1,4-dione 
• 1329428-61-6 C₁₃H₁₈O₃ 
• 670260-41-0 (R)-1-(2,5-dimethoxy-4-methylphenyl)ethyl diisopropylcarbamate 

Relevant academic research and scientific papers

Enantioselective total synthesis of heliespirone B

The first enantiocontrolled total synthesis of heliespirone B has been accomplished employing a biomimetic intramolecular oxy-Michael reaction followed by the regio- and diastereoselective reduction of the carbonyl function as key steps.

Enantioselective syntheses of the assigned structures of the helibisabonols A and B

The enantioselective syntheses of the compounds with the assigned structures of the helibisabonols A and B have been accomplished. Using an enzymatic desymmetrization of the σ-symmetrical diol (route a) and a diastereoselective conjugate addition of the m

An efficient total synthesis of (+)-heliannuol D

An efficient total synthesis of (+)-heliannuol D was accomplished in 14 steps and in 12% overall yield by employing a diastereoselective conjugate addition reaction to create a tertiary benzylic stereogenic center and simple assembly of the functionalized oxepane framework by an efficient one-pot transformation procedure as the key steps.