126014-70-8

Upstream product

• 3532-17-0 4-methoxybenzoyl azide 
• 106-95-6 allyl bromide 
• 121-98-2 methyl 4-methoxybenzoate 
• 1730-25-2 allylmagnesium bromide 
• 18925-10-5 allylzinc bromide 
• 100-07-2 4-methoxy-benzoyl chloride 

Downstream Products

• 224191-89-3 1-(4-allylhepta-1,6-dien-4-yl)-4-methoxybenzene 

Relevant academic research and scientific papers

Solvent- and catalyst-free gem-bisallylation of carboxylic acid derivatives with allylzinc bromide

A rapid and efficient procedure for the solvent-free synthesis of gem-bisallylation products has been achieved by allylzinc bromide with carboxylic acid derivatives in the absence of any catalysts at room temperature.

Fast and scalable route to aryl polyallyl dendrons and dendrimers

In the quest for general and efficient synthetic procedures for dendrons and dendrimers, allylphenol, allylnaphthol and 6-bromonaphthalene AB3 dendrons have been successfully prepared on a large-scale by a rapid and clean route starting from commercially available esters and allyl bromide. In contrast to the known organoiron strategy, the above-mentioned methodology enables the large-scale synthesis of AB3 dendrons in only two days.

Gem-diallylation of acyl azides with allylsamarium bromide under mild conditions

Allylsamarium bromide reacts with acyl azides to give the corresponding gem-diallylation products, 4-alkyl-1,6-heptadienes-4-ols (3), in good to excellent yields. This novel reaction proceeds readily within a few minutes at room temperature.