3532-17-0

Basic information

• Product Name: Benzoyl azide, 4-methoxy-
• CAS NO: 3532-17-0
• Molecular Formula: C8H7N3O2
• Molecular Weight: 177.162
• Mol File: 3532-17-0.mol
• Article Data: 49

Chemical Properties

• CAS DataBase Reference: Benzoyl azide, 4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl azide, 4-methoxy-(3532-17-0)
• EPA Substance Registry System: Benzoyl azide, 4-methoxy-(3532-17-0)

Safety Data

• Hazardous Substances Data: 3532-17-0(Hazardous Substances Data)

Upstream product

• 3290-99-1 4-methoxybenzoic acid hydrazide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 50-00-0 formaldehyd 
• 696-62-8 para-iodoanisole 
• 133214-18-3 CH₃OC₆H₄COCH₂COC₄H₃O 
• 57114-82-6 (2-naphthoyl)-(4-methoxybenzoyl)methane 
• 37975-18-1 1-(4-bromophenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 37975-19-2 1-(4-chlorophenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 80370-28-1 1-(3,4-dimethoxy-phenyl)-3-(4-methoxy-phenyl)-propane-1,3-dione 
• 252965-04-1 1-(3-methoxyphenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 70356-09-1 1-(4-methoxyphenyl)-3-(4-tert-butylphenyl)propane-1,3-dione 
• 25856-03-5 1-(4-methoxy-phenyl)-3-p-tolyl-propane-1,3-dione 
• 6327-79-3 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione 
• 18362-51-1 1,3-bis(4'-methoxyphenyl)propane-1,3-dione 

Downstream Products

• 5416-93-3 4-Methoxyphenyl isocyanate 
• 107771-08-4 (4-methoxy-phenyl)-carbamic acid-(2-diethylamino-ethyl ester) 
• 10367-84-7 N,N-diethylamino ethyl p-methoxybenzoate 
• 7465-87-4 N-benzyl-4-methoxybenzamide 
• 63697-32-5 5-methoxy-2-(4-methoxy-phenyl)-4,4-dimethyl-4,5-dihydro-oxazole 
• 38388-66-8 5-ethoxy-2-(4-methoxy-phenyl)-4,4-dimethyl-4,5-dihydro-oxazole 
• 91593-31-6 (7S,9S)-7,8,9,10-tetrahydro-6,7,9,11-terahydroxy-9-<<<(4-methoxyphenyl)carbamoyl>oxy>methyl>-5,12-naphthacenedione 
• 3424-93-9 4-methoxyphenylacetamide 
• 1227-44-7 N,N'-bis(4-methoxyphenyl)urea 
• 330816-29-0 C₂₈H₂₅N₂O₄P 
• 126014-70-8 4-(4-methoxyphenyl)hepta-1,6-dien-4-ol 
• 20950-96-3 (4-methoxyphenyl)carbamic acid phenyl ester 
• 58734-14-8 4-methoxy-N-tosylbenzamide 
• 91591-22-9 (4-Methoxy-phenyl)-carbamic acid (2S,4S)-2,5,12-trihydroxy-4-[(2R,4S,5S,6S)-5-hydroxy-6-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-2-yloxy]-6,11-dioxo-1,2,3,4,6,11-hexahydro-naphthacen-2-ylmethyl ester 

Relevant articles and documents

Facile consecutive three-component synthesis of 3,5-disubstituted isoxazoles

[Figure not available: see fulltext.] 3,5-Di(hetero)aryl-substituted isoxazoles can be rapidly synthesized in a one-pot fashion by a consecutive three-component alkynylation–cyclization sequence starting from (hetero)aroyl chloride, alkynes, and sodium azide/acetic acid under copper-free palladium catalysis as exemplified by 9 different products.

Synthesis of: N -methylated amines from acyl azides using methanol

The transformation of acyl azide derivatives into N-methylamines was developed using methanol as the C1 source via the one-pot Curtius rearrangement and borrowing hydrogen methodology. Following this protocol, various functionalised N-methylated amines were synthesized using the (NNN)Ru(ii) complex from carboxylic acids via an acyl azide intermediate. Several kinetic studies and DFT calculations were carried out to support the mechanism and also to determine the role of the Ru(ii) complex and base in this transformation.

Synthesis of Acyl Azides from 1,3-Diketones via Oxidative Cleavage of Two C-C Bonds

A metal-free PhI(OAc)2-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.