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1260183-52-5

(1-(4-fluorophenyl)ethoxy)trimethylsilane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1260183-52-5 Structure

  • Basic information

    1. Product Name: (1-(4-fluorophenyl)ethoxy)trimethylsilane
    2. Synonyms: (1-(4-fluorophenyl)ethoxy)trimethylsilane
    3. CAS NO:1260183-52-5
    4. Molecular Formula:
    5. Molecular Weight: 212.339
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1260183-52-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1-(4-fluorophenyl)ethoxy)trimethylsilane(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1-(4-fluorophenyl)ethoxy)trimethylsilane(1260183-52-5)
    11. EPA Substance Registry System: (1-(4-fluorophenyl)ethoxy)trimethylsilane(1260183-52-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1260183-52-5(Hazardous Substances Data)

1260183-52-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1260183-52-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,6,0,1,8 and 3 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1260183-52:
(9*1)+(8*2)+(7*6)+(6*0)+(5*1)+(4*8)+(3*3)+(2*5)+(1*2)=125
125 % 10 = 5
So 1260183-52-5 is a valid CAS Registry Number.

1260183-52-5Relevant articles and documents

Synthetic Versatility of Lipases: Application for Si-O Bond Formation and Cleavage

Brondani, Patrícia Bulegon,Mittersteiner, Mateus,Voigt, Morgana Aline,Klinkowski, Bruna Heloisa,Riva Scharf, Dilamara,De Jesus, Paulo Cesar

, p. 477 - 485 (2019)

Several commercially available lipases were examined in a study on O-Si bond formation and cleavage applying silicon-based protecting groups and alcohols or the corresponding silyl ethers. With regard to deprotection, from silyl ether to the corresponding alcohol, only the solvent and the lipase were necessary. The influence of the protecting group, the lipase source, and the substituent was investigated to optimize the results. The TMS moiety could be removed in 24 hours of reaction at room temperature in aqueous systems (conv. up to 99%, depending on the substrate and lipase). The reverse reactions, that is, with the protection of the alcohols, were carried out in hexane using different silyl chlorides. The TMS, TES, and TBS moieties were successfully inserted in the primary and secondary alcohols without the need for dry conditions or an inert atmosphere, presenting conversions of up to 99%, depending on the substrate.

FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers

Khan, Imtiaz,Reed-Berendt, Benjamin G.,Melen, Rebecca L.,Morrill, Louis C.

, p. 12356 - 12359 (2018/09/18)

Herein we report the first catalytic transfer hydrogenation of silyl enol ethers. This metal free approach employs tris(pentafluorophenyl)borane and 2,2,6,6-tetramethylpiperidine (TMP) as a commercially available FLP catalyst system and naturally occurring γ-terpinene as a dihydrogen surrogate. A variety of silyl enol ethers undergo efficient hydrogenation, with the reduced products isolated in excellent yields (29 examples, 82 % average yield).

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