1262057-02-2Relevant articles and documents
Selective synthesis of indazoles and indoles via triazene-alkyne cyclization switched by different metals
Fang, Yan,Wang, Chengming,Su, Shengqin,Yu, Haizhu,Huang, Yong
, p. 1061 - 1071 (2014/02/14)
We described two orthogonal heterocycle syntheses, where an arene bearing both an alkyne and a triazene functionality underwent two distinct cyclization pathways mediated by different transition metals. Starting from the same substrates, a synthesis of 2H
Richter cyclization and co-cyclization reactions of triazene-masked diazonium ions
Goeminne, Annelies,Scammells, Peter J.,Devine, Shane M.,Flynn, Bernard L.
supporting information; experimental part, p. 6882 - 6885 (2011/03/18)
The conventional Richter cyclization involves diazotization of 2-alkynylanilines with HX (aq) (X = Br or Cl) and NaNO2, followed by spontaneous ring closure to give a mixture of 4-halocinnoline and 4-cinnolinone products. The different products