1262848-08-7Relevant academic research and scientific papers
Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol
Hama, Naoto,Aoki, Toshihiro,Miwa, Shohei,Yamazaki, Miki,Sato, Takaaki,Chida, Noritaka
, p. 616 - 619 (2011/04/15)
A first total synthesis of broussonetine F from diethyl l-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.
