126330-74-3

Basic information

• Product Name: 2-Pyridyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside
• Synonyms: 2-Pyridyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside
• CAS NO: 126330-74-3
• Molecular Weight: 527.684
• Mol File: 126330-74-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Pyridyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside(126330-74-3)
• EPA Substance Registry System: 2-Pyridyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside(126330-74-3)

Safety Data

• Hazardous Substances Data: 126330-74-3(Hazardous Substances Data)

Upstream product

• 2127-03-9 2,2'-dipyridyldisulphide 
• 210426-02-1 2,3,4-tri-O-benzyl-L-rhamnopyranose 
• 100-39-0 benzyl bromide 
• 2637-34-5 2-Sulfanylpyridine 
• 136984-94-6 2-pyridyl 2,3,4-tri-O-acetyl-1-thio-α/β-L-rhamnoyranoside 
• 5158-64-5 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide 
• 162118-38-9 (3S,4R,5R,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-ol 
• 199851-12-2 2-Pyridyl 1-thio-α-L-fucopyranoside 
• 199850-98-1 2-Pyridyl 2,3,4-tri-O-acetyl-1-thio-β-L-fucopyranoside 
• 16741-27-8 2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide 

Downstream Products

• 71672-13-4 2,3,4-tri-O-benzyl-α-L-fucopyanosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 64694-29-7 1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl 2,3,4-tri-O-benzyl-α-L-fucopyranose 
• 196941-73-8 benzyl 2-acetamido-4,6-O-benzylidene-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-2-deoxy-α-D-glucopyranoside 
• 126330-72-1 (3aR,4R,6S,7S,7aR)-4-Methoxy-2,2,6-trimethyl-7-((2S,3R,4R,5S,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 126330-71-0 6-O-(2,3,4-tri-O-benzyl-L-rhamnopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 

Relevant articles and documents

Stereoselective synthesis of α-O-fucosylated serine, threonine, tyrosine and saccharides

Stereoselectiye fucosylation of Boc-Ser/Thr/Tyr-OMe 2-4 and several saccharide alcohols 5-7 by coupling with 2-pyridyl tri-O-benzyl-1-thio-β-L-fucosyl donor 1b under iodomethane activation procedure results in the formation of α-linked fucosylated amino a

A MILD GENERAL METHOD FOR THE SYNTHESIS OF α-LINKED DISACCHARIDES

Stereoselective α-glycosylations may be achieved using stable 2-pyridyl thioglycosides (anomeric mixture) having a non-participating 2-substituent as glycosyl donor and methyl iodide as an activator.