1263574-40-8Relevant articles and documents
Asymmetric α-amination of 4-substituted pyrazolones catalyzed by a chiral Gd(OTf)3/ N,N′-dioxide complex: Highly enantioselective synthesis of 4-amino-5-pyrazolone derivatives
Yang, Zhigang,Wang, Zhen,Bai, Sha,Liu, Xiaohua,Lin, Lili,Feng, Xiaoming
, p. 596 - 599 (2011)
The asymmetric α-amination of 4-substituted pyrazolones with azodicarboxylates was investigated for the first time, employing an N,N′-dioxide gadolinium(III) complex as the catalyst. The novel transformations exhibited high yield, and 4-amino-5-pyrazolone