1266551-59-0

Basic information

• Product Name: (E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-one
• Synonyms: (E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-one
• CAS NO: 1266551-59-0
• Molecular Weight: 288.505
• Mol File: 1266551-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-one(1266551-59-0)
• EPA Substance Registry System: (E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-one(1266551-59-0)

Safety Data

• Hazardous Substances Data: 1266551-59-0(Hazardous Substances Data)

Upstream product

• 18328-11-5 3-benzyl propionaldehyde 
• 120943-70-6 dimethyl <2-(tert-butyldimethylsilyl)-2-oxoethyl>-phosphonate 
• 3360-41-6 4-phenyl-butan-1-ol 

Downstream Products

• 1266551-75-0 (S,E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-ol 
• 1266551-30-7 (R,E)-1-(tert-butyl-dimethylsilyl)-6-phenylhex-2-en-1-ol 
• 1266551-60-3 C₂₈H₃₇F₃O₃Si 
• 1296209-62-5 C₂₈H₃₇F₃O₃Si 

Relevant articles and documents

Stereoselective anti-SN2′ Mitsunobu reaction of α-hydroxy-α-alkenylsilanes

A novel silyl group-directed anti-SN2′ reaction of allylic alcohols under Mitsunobu reaction conditions is described. The Mitsunobu reaction of α-hydroxy-α-alkenylsilanes with a TBS or TIPS group gave the anti-SN2′ product, in which regio- and stereochemical outcomes of the reaction depended on the steric bulkiness of the silyl group.