126705-57-5

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 126705-59-7 methyl 3-(5'-acetyl-2'-methoxyphenyl)propanoate 
• 126705-58-6 methyl 3-<5'-(1''-hydroxyethyl)-2'-methoxyphenyl>propanoate 
• 79324-77-9 1‐(3‐iodo‐4‐methoxyphenyl)ethan‐1‐one 
• 157953-19-0 1-[3-(3-Hydroxy-3-methyl-but-1-ynyl)-4-methoxy-phenyl]-ethanone 
• 126705-61-1 4-<5'-(1'-hydroxyethyl)-2-methoxyphenyl>-2-methyl-butan-2-ol 

Downstream Products

• 26931-99-7 1-(4-methoxy-3-(3-methylbut-2-enyl)phenyl)ethanone 

Relevant academic research and scientific papers

REGIOSELECTIVE PRENYLATION OF PHENOLS BY PALLADIUM CATALYST: SYNTHESES OF PRENYLPHENOLS AND CHROMANS

The palladium-catalyzed coupling reaction of iodophenols (1) with 2-methyl-3-butyn-2-ol gave alkynylphenols (2).Catalytic hydrogenation of 2 over Raney nickel and the subsequent dehydration of the resultant alkylphenols (3) gave regioselectively the desired prenylphenols (4).Dehydration of alkylphenols (3f-h) gave chromans (7).

Synthesis of two meroterpenic acetophenones occurring in Senecia and Helianthella species

Starting from the common synthon, methyl 3-propanoate (4), the syntheses of two naturally occurring meroterpenes, 4-hydroxy-3-(3'-hydroxyisopentyl)acetophenone (1) and 3-(2-isopenten-1-yl)-4-methoxyacetophenone (3)