126741-72-8

Upstream product

• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 1402934-50-2 3-tert-butyl(3-methoxymethoxy-3-phenylprop-1-ynyl)diphenylsilane 
• 129758-81-2 (1-methoxymethoxyprop-2-ynyl)benzene 
• 100-52-7 benzaldehyde 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 112440-16-1 1-<(1',1'-dimethylethyl)diphenylsilyl>acetylene 

Downstream Products

• 1402934-51-3 3-(tert-butyldiphenylsilanyl)-1-phenyl-prop-2-en-1-ol 
• 1402934-52-4 3-(tert-butyldiphenylsilanyl)-1-phenyl-propen-1-one 
• 126741-89-7 2-<(1',1'-dimethylethyl)diphenylsilylmethyl>-3-hydroxy-3-phenylpropanal 
• 123628-95-5 2-<(1',1'-dimethylethyl)diphenylsilylmethyl>-3-trimethylsilyloxypropanal 
• 123628-89-7 (Z)-1-<(1',1'-dimethylethyl)diphenylsilyl>-3-trimethylsilyloxyprop-1-ene 
• 126741-76-2 (Z)-1-<(1',1'-dimethylethyl)diphenylsilyl>-3-phenylprop-1-en-3-ol 

Relevant academic research and scientific papers

Novel sequential 1,4-Brook rearrangement-Wittig reaction: New one-pot approach for silyl dienol ethers

A novel one-pot synthetic method of silyl dienol ethers via 1,4-Brook rearrangement-Wittig reaction sequence has been developed. This tandem reaction proceeded via the intramolecular silyl migration step, which enabled stereoselective formation of phosphorane intermediates. The reaction is operationally simple and high yielding, thus providing a new useful formula for silyl dienol ether synthesis.

The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes

The regiochemistry of hydroformylation of alkenes can be controlled by use of bulky silyl groups attached to the alkene.Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.