1267597-10-3Relevant academic research and scientific papers
Biocatalytic Approach for the Total Synthesis of (-)-Malyngolide and Its C(5)-Epimer
Srivastava, Nikhil,Subba Reddy, Basi V.
, p. 267 - 272 (2016/05/02)
An enzymatic approach has been successfully utilized in the total synthesis of (-)-malyngolide and its C(5)-epimer. The required configuration was established by an enzymatic kinetic resolution and Sharpless asymmetric dihydroxylation.
Fluorine in fragrances: Exploring the difluoromethylene (CF2) group as a conformational constraint in macrocyclic musk lactones
Corr, Michael J.,Cormanich, Rodrigo A.,Von Hahmann, Cortney N.,Bühl, Michael,Cordes, David B.,Slawin, Alexandra M. Z.,O'Hagan, David
, p. 211 - 219 (2015/12/30)
The CF2 group is incorporated into specific positions within the lactone ring of the natural musk lactone, (12R)-(+)-12-methyl-13-tridecanolide, a constituent of Angelica root oil, Angelica archangelica L. The approach is taken as it was antici
Probing the influence of an allylic methyl group in zearalenone analogues on binding to Hsp90
Rink, Christian,Sasse, Florenz,Zubrienae -, Asta,Matulis, Daumantas,Maier, Martin E.
, p. 14469 - 14478 (2011/03/21)
By the replacement of an acetate with propionate by means of organic synthesis, a range of zearalenone analogues were prepared that feature an allylic methyl group. For the synthesis of the aliphatic region of the analogues, we used an asymmetric alkylati
