1267636-78-1

Basic information

• Product Name: 3-(3-chlorobenzoyl)benzaldehyde
• Synonyms: 3-(3-chlorobenzoyl)benzaldehyde
• CAS NO: 1267636-78-1
• Molecular Weight: 244.677
• Mol File: 1267636-78-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(3-chlorobenzoyl)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-chlorobenzoyl)benzaldehyde(1267636-78-1)
• EPA Substance Registry System: 3-(3-chlorobenzoyl)benzaldehyde(1267636-78-1)

Safety Data

• Hazardous Substances Data: 1267636-78-1(Hazardous Substances Data)

Upstream product

• 71372-41-3 (3-chlorophenyl)(m-tolyl)methanone 
• 535-80-8 3-chlorobenzoate 
• 145959-21-3 3-chloro-N-methoxy-N-methylbenzamide 
• 1385033-52-2 3-(3-chlorobenzoyl)benzonitrile 

Downstream Products

• 1314314-59-4 (3Z,6Z)-3-((5-tert-butyl-1H-imidazol-4-yl)methylene)-6-(3-(3-chlorobenzoyl)benzylidene)piperazine-2,5-dione 

Relevant articles and documents

Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)-H Oxygenation

We report the first example of RhII-catalyzed chemoselective double C(sp3)-H oxygenation, which can directly transform various toluene derivatives into highly valuable aromatic aldehydes with great chemoselectivity and practicality. The critical combination of catalyst Rh(OAc)2, oxidant Selectfluor, and solvents of TFA/TFAA promises the successful delivery of the oxidation with satisfactory yields. A possible mechanism involving a unique carbene-Rh complex is proposed, and has been supported by both experiments and theoretical calculations.