126786-46-7

Upstream product

• 55955-33-4 2,3-di-O-benzyl-1-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)glycerol 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 22160-25-4 3-O-β-D-glucopyranosyl-sn-glycerol 
• 55955-33-4 2,3-di-O-benzyl-1-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)glycerol 

Downstream Products

• 84799-77-9 methyl 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 20196-71-8 (2S)-2,3-bis(benzyloxy)propanol 

Relevant academic research and scientific papers

Simple Method to Detrermine the Absolute Configuration of the Glycerol Moiety in Glycosyl Glycerols Based On ORD and CD

A general method to determine the absolute configuration of the glycerol moiety in glycopyranosyl glycerols is presented, which involves per-O-benzylation and acid hydrolysis of the glycosyl glycerol to give optically active 1,2- or 2,3-di-O-benzylated sn-glycerol (III).ORD and CD measurements of III and its benzoylated derivatives gave intensive optical rotations or Cotton effects to determine the absolute configuration at C2.

SEPARATION OF RACEMATES OF 1,2-DISUBSTITUTED DERIVATIVES OF GLYCEROL INTO ANTIPODES

1,2-Di-O-Benzyl-rac-glycerol (or 1-stearoyl-2-O-benzyl-rac-glycerol) was glycocylated with acetobromoglucose or mannose tert-butyl orthoacetate.The chromatographic chasracteristics of the synthesized 1,2-trans-glycosides and of the glycosides obtained by