1268519-04-5Relevant articles and documents
Enantioselective addition of diethylzinc to aromatic aldehydes catalyzed by C2-symmetric chiral diols
G?k, Ya?ar,Keke?, Levent
, p. 2727 - 2729 (2014)
Optically pure C2-symmetric diols have been synthesized with moderate yields in a straightforward manner, and are used as catalysts in the enantioselective alkylation of aromatic aldehydes with diethylzinc. The addition of diethylzinc to benzal
A novel C2-symmetric bisphosphane ligand with a chiral cyclopropane backbone: Synthesis and application in the Rh(I)-catalyzed asymmetric 1,4-addition of arylboronic acids
Goek, Yaar,Noel, Timothy,Eycken, Johan Van Der
experimental part, p. 2768 - 2774 (2011/03/18)
The synthesis of a novel C2-symmetric bisphosphane ligand was accomplished starting from trans-(2R,3R)-bis(3′,5′-diphenylphenyl) cyclopropane-1,1-dimethanol as a key intermediate. This ligand was tested in the asymmetric rhodium(I)-catalyzed 1,