1268519-08-9

Upstream product

• 363622-48-4 1,3-dibromo-5-[(diethylphosphonyl)methyl]benzene 
• 120359-56-0 3,5-dibromostyrene 
• 56908-88-4 3,5-dibromobenzyl bromide 
• 56990-02-4 3,5-dibromobenzaldehyde 
• 1611-92-3 3,5-dibromotoluene 
• 1268519-07-8 (2R,3R)-1-(ethoxycarbonyl)-2,3-bis(3',5'-dibromophenyl)cyclopropane-1-carboxylic acid 
• 1268519-05-6 (4R,5R)-4,5-bis(3',5'-dibromophenyl)-(1,3,2)-dioxathiolane-2,2-dioxide 
• 1268519-04-5 (1R,2R)-1,2-bis(3,5-dibromophenyl)ethane-1,2-diol 

Downstream Products

• 1268519-10-3 (2R,3R)-1,1-bis(chloromethyl)-2,3-bis(3',5'-diphenylphenyl)cyclopropane 
• 1268519-03-4 (2R,3R)-1,1-bis[(diphenylphosphanyl)methyl]-2,3-bis(3',5'-diphenylphenyl)cyclopropane 
• 1268519-09-0 (2R,3R)-2,3-bis(3',5'-diphenylphenyl)cyclopropane-1,1-dimethanol 

Relevant academic research and scientific papers

A novel C2-symmetric bisphosphane ligand with a chiral cyclopropane backbone: Synthesis and application in the Rh(I)-catalyzed asymmetric 1,4-addition of arylboronic acids

The synthesis of a novel C2-symmetric bisphosphane ligand was accomplished starting from trans-(2R,3R)-bis(3′,5′-diphenylphenyl) cyclopropane-1,1-dimethanol as a key intermediate. This ligand was tested in the asymmetric rhodium(I)-catalyzed 1,