126884-42-2Relevant academic research and scientific papers
REACTION OF PERCHLORO-5-METHYLENE-2-CYCLOPENTENE-1,4-DIONE WITH THIOAMIDE NUCLEOPHILES
Talzi, V. P.,Bek, N. O.,Gudoshnikov, S. K.,Safarova, V. I.
, p. 688 - 690 (2007/10/02)
In the reaction of perchloro-5-methylene-2-cyclopentene-1,4-dione with dimethylthioformamide and S-ethyl dimethylthiocarbamate the corresponding salts of the cations of amidothiol ethers are formed as a result of nucleophilic substitution of the two chlorine atoms of the chloromethylene group by two molecules of the thioamide nucleophiles.In the reaction of perchloro-5-methylene-2-cyclopentene-1,4-dione with tetramethylthiuram disulfide the diketone molecule condenses with one thiuram molecule, and hydrogen chloride is eliminated.
