126899-99-8

Upstream product

• 33704-38-0 2-(benzylsulfinothioyl)isoindoline-1,3-dione 
• 122952-01-6 C₁₉H₁₈O₅S 
• 126925-52-8 13-((E)-2-mercaptoethylidene)spirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolane>-1,8-diol 
• 122951-97-7 1,8-dihydroxyspirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolan>-13-one 
• 122951-96-6 13-(hydroxymethyl)spirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolane>-1,8,13-triol 
• 122951-98-8 (diethoxyphosphinyl)acetic acid, 9-hydroxy-13-oxospirotrideca-5,12-diene-3,7-diyne-11,2'-<1,3>dioxolan>-2-yl ester 
• 122952-01-6 ethanethioic acid, (S)-2-(1,8-dihydroxyspirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolan>-13-ylidene)ethyl ester 
• 122951-95-5 13-<(acetyloxy)methyl>spirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolane>-1,8,13-triol 
• 122968-00-7 C₁₇H₁₄O₅ 
• 122951-99-9 5',6'-dihydro-5'-hydroxyspiro<1,3-dioxolane-2,7'-(3'H)-<1,5><3>hexene<1,5>diyno<1H-2>benzopyran>-3'-one 
• 122952-00-5 13-<(E)-2-hydroxyethylidene>spirotrideca-4,9-diene-2,6-diyne-11,2'-<1,3>dioxolane>-1,8-diol 
• 122952-00-5 C₁₇H₁₆O₅ 

Downstream Products

• 126900-01-4 1,8-dihydroxy-13-<(E)-2-<(phenylmethyl)trithio>ethylidene>bicyclo<7.3.1>trideca-4,9-diene-2,6-diyn-11-one 
• 126900-01-4 C₂₂H₁₈O₃S₃ 

Relevant academic research and scientific papers

Total synthesis of calicheamicinone: New arrangements for actuation of the reductive cycloaromatization of aglycon congeners

The total synthesis of dl-calicheamicinone (1) has been accomplished. The key elements of the synthesis were (i) an application of the Becker-Adler reaction to reach compound 91, (ii) an application of the concept of in situ protection to deliver lithiate

Installation of the Allylic Trisulfide Functionality of the Enediyne Antibiotics. Thiol-Induced Reductive Actuation of the Bergman Process

The title compounds were synthesized through thiosulfenylation.Exposure of the trisulfides to benzyl mercaptan induced reductive cycloaromatization.