1269207-66-0

Basic information

• Product Name: N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide
• Synonyms: N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide
• CAS NO: 1269207-66-0
• Molecular Weight: 357.26
• Mol File: 1269207-66-0.mol

Chemical Properties

• CAS DataBase Reference: N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide(1269207-66-0)
• EPA Substance Registry System: N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide(1269207-66-0)

Safety Data

• Hazardous Substances Data: 1269207-66-0(Hazardous Substances Data)

Upstream product

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 2234-16-4 1-(2,4-dichlorophenyl)ethan-1-one 

Downstream Products

• 1269207-29-5 2-(1-(2,4-dichlorophenyl)ethyl)-4,5-dimethylthiazole 
• 1269207-20-6 2-(1-(2,4-dichlorophenyl)ethyl)benzo[d]thiazole 
• 1430811-49-6 N-(1-(2,4-dichlorophenyl)ethyl)-N'-(1-(2,4-dichlorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide 
• 1440537-96-1 1-(1-(2,4-dichlorophenyl)vinyl)-1H-indole 

Relevant articles and documents

Directed C-C bond cleavage of a cyclopropane intermediate generated from: N -tosylhydrazones and stable enaminones: Expedient synthesis of functionalized 1,4-ketoaldehydes

An efficient method to construct functionalized 1,4-ketoaldehydes bearing all-carbon α-quaternary centers via regioselective C-C bond activation has been described. The cyclopropanation of bench-stable enaminones with in situ generated diazo reagents from

Copper(I)-Catalyzed Alkylation of Polyfluoroarenes through Direct C - H Bond Functionalization

The copper(I)-catalyzed alkylation of electron-deficient polyfluoroarenes with N-tosylhydrazones and diazo compounds has been developed. This reaction uses readily available starting materials and is operationally simple, thus representing a practical method for the construction of C(sp2) - C(sp3) bonds with polyfluoroarenes through direct C - H bond functionalization. Mechanistically, copper(I) carbene formation and subsequent migratory insertion are proposed as the key steps in the reaction pathway.

Palladium-catalyzed oxidative cross-coupling of N-tosylhydrazones with indoles: Synthesis of N-vinylindoles

A general and efficient palladium-catalyzed oxidative cross-coupling reaction of N-tosylhydrazones with indoles providing N-vinylindoles has been developed. The reaction proceeds smoothly with various indoles and N-tosylhydrazones in a stereocontrolled ma

Copper-catalyzed direct benzylation or allylation of 1,3-azoles with N -tosylhydrazones

Cu-Catalyzed cross-coupling of N-tosylhydrazones with 1,3-azoles leads to the direct C-H benzylation or allylation. Cu carbene migratory insertion is proposed to play the key role in this transformation.