1269626-89-2Relevant academic research and scientific papers
Trapping the oxyallyl cation intermediate derived from the Nazarov cyclization of allenyl vinyl ketones with nitrogen heterocycles
Marx, Vanessa M.,Lefort, Francois M.,Burnell, D. Jean
experimental part, p. 64 - 68 (2011/03/22)
The cationic intermediate of the Lewis acid-initiated Nazarov cyclization of an allenyl vinyl ketone (AVK) was trapped by pyrroles and indoles. The yields ranged from modest to high (up to 93%), and in both cases, only two of the three possible products w
