1270304-91-0Relevant articles and documents
Asymmetric synthesis of tertiary and quaternary allyl- and crotylsilanes via the borylation of lithiated carbamates
Aggarwal, Varinder K.,Binanzer, Michael,De Ceglie, M. Carolina,Gallanti, Maddalena,Glasspoole, Ben W.,Kendrick, Stephanie J. F.,Sonawane, Ravindra P.,Vazquez-Romero, Ana,Webster, Matthew P.
, p. 1490 - 1493 (2011)
Tertiary allyl- or crotylsilanes have been prepared in high er and dr via the lithiation-borylation reaction of alkyl carbamates with silaboronates. Using a related strategy, quaternary allylsilanes could be accessed in similarly high er.