127135-74-4

Upstream product

• 127135-72-2 (R)-1-[(2S,3R)-3-(1-Hydroxy-1-methyl-ethyl)-oxiranyl]-2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-prop-2-en-1-ol 
• 7143-01-3 Methanesulfonic anhydride 
• 127135-70-0 (E)-(S)-2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-6-methyl-6-triethylsilanyloxy-hepta-1,4-dien-3-ol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 127182-28-9 (1R,3R,3aR,3bR,4R,6aS,6bR)-3-(1-Hydroxymethyl-vinyl)-4,6b-dimethyl-decahydro-cyclobutadicyclopenten-1-ol 
• 132101-60-1 tert-Butyl-{2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-allyloxy}-dimethyl-silane 
• 132101-61-2 2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-prop-2-en-1-ol 
• 132101-59-8 (1R,3R,3aR,3bR,4R,6aS,6bR)-3-[1-(tert-Butyl-dimethyl-silanyloxymethyl)-vinyl]-4,6b-dimethyl-decahydro-cyclobutadicyclopenten-1-ol 
• 127135-69-7 C₁₁H₂₃LiOSi 
• 127135-71-1 (E)-(S)-6-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-2-methyl-5-triethylsilanyloxy-hepta-3,6-dien-2-ol 
• 127135-76-6 (E)-(S)-6-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-2-methyl-hepta-3,6-diene-2,5-diol 
• 127156-24-5 2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-propenal 

Downstream Products

• 132101-62-3 4-Oxo-pentanoic acid (S)-1-[(2S,3R)-3-(1-hydroxy-1-methyl-ethyl)-oxiranyl]-2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-allyl ester 
• 127135-75-5 (2S,2'S,3'S)-3'-{1-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-vinyl}-3,3-dimethyl-[2,2']bioxiranyl 
• 76520-52-0 (+)-spatol 
• 127135-75-5 (2S,2'S,3'R)-3'-{1-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-Methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-vinyl}-3,3-dimethyl-[2,2']bioxiranyl 
• 132199-68-9 (S)-1-[(2S,3R)-3-(1-Hydroxy-1-methyl-ethyl)-oxiranyl]-2-[(1R,3R,3aR,3bS,6R,6aR,6bR)-3-(4-methoxy-benzyloxy)-3a,6-dimethyl-decahydro-cyclobutadicyclopenten-1-yl]-prop-2-en-1-ol 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF (+)-SPATOL. A STEREOSPECIFIC CONSTRUCTION OF VICINAL DIEPOXIDES FROM 2,3-EPOXY-1,4-DIOLS

A total synthesis of (+)-spatol (1) was achived which depends upon a novel stereospecific transformation of trans-2,3-epoxy-1,4-diols to generate sensitive allylic vicinal cis-epoxide in 1.