1272675-50-9Relevant academic research and scientific papers
A New Simplified Protocol for Copper(I) Alkyne-Azide Cycloaddition Reactions Using Low Substoichiometric Amounts of Copper(II) Precatalysts in Methanol
Buckley, Benjamin R.,Figueres, Maria M. P.,Khan, Amna N.,Heaney, Harry
, p. 51 - 56 (2016)
Copper(II) carboxylates are reduced efficiently by methanol in the presence of alkynes and form yellow alkynylcopper(I) polymeric precatalysts that are involved with azides, in the absence of added ligands, in the catalytic cycles that result in the forma
Heterogeneous catalytic reactions "on Water" by using stable polymeric alkynylcopper(I) pre-catalysts: Alkyne/azide cycloaddition reactions
Buckley, Benjamin R.,Dann, Sandra E.,Heaney, Harry,Stubbs, Emma C.
supporting information; experimental part, p. 770 - 776 (2011/03/22)
Dinuclear alkynylcopper(I) complexes have been found to be the active pre-catalysts in copper-catalysed cycloaddition of azides and terminal alkynes (CuAAC). These copper(I) ladderane polymers are used in "on water" CuAAC reactions, with loadings as low a
