127275-05-2

Upstream product

• 20684-76-8 4-<(Diphenylphosphinoyl)methyl>morpholine 
• 127275-03-0 (4R,5S)-2,2-Dimethyl-5-((Z)-oct-2-enyl)-[1,3]dioxolane-4-carbaldehyde 
• 108817-97-6 (4R,5S)-5-tert-butyldimethylsilyloxymethyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 
• 127275-01-8 1-[(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2-(diphenyl-phosphinoyl)-2-morpholin-4-yl-ethanol 
• 127275-02-9 tert-Butyl-[(4S,5S)-2,2-dimethyl-5-((Z)-oct-2-enyl)-[1,3]dioxolan-4-ylmethoxy]-dimethyl-silane 
• 127275-00-7 [(4S,5S)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetaldehyde 
• 108817-96-5 [(4S,5S)-5-[(tert-butyl(dimethyl)silyl)oxymethyl]-2,2-dimethyl-1,3-dioxolan-4-yl]methanol 
• 127309-18-6 [(4S,5S)-2,2-Dimethyl-5-((Z)-oct-2-enyl)-[1,3]dioxolan-4-yl]-methanol 
• 50622-09-8 2,3-O-isopropylidene-L-threitol 
• 4762-26-9 hexyltriphenylphosphonium bromide 
• 59779-75-8 diethyl (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate 

Relevant academic research and scientific papers

SYNTHESIS OF 12-HYDROPEROXYEICOSATETRAENOIC ACID (12-HPETE). ON THE STEROCHEMISTRY IN THE CONVERSION OF 12(S)-HETE TO 12-HPETE

12(S)-hydroxyeicosatetraenoic acid methyl ester 1 was synthesized. 1 was converted to phosphite 17 which upon treatment with hydrogen peroxide afforded the corresponding hydroperoxide 18 (12-HPETE methyl ester) with partially retained configuration.