127451-52-9Relevant academic research and scientific papers
DIASTEREOCONTROLLED NICKEL(O)- AND PALLADIUM(O) CATALYZED "METALLO-ENE-TYPE" CYCLIZATIONS/CARBONYLATIONS
Oppolzer, Wolfgang,Keller, Thomas H.,Bedoya-Zurita, Manuel,Stone, Charles
, p. 5883 - 5886 (1989)
Treatment of 1-iodo(acetoxy)-2,7-octadienes 1 and 1-iodo(acetoxy)-2-en-7-ynes 12 with Ni(COD)2/dppb (THF/MeOH) or Pd(dba)2/PPh3 (AcOH, then CH2N2) under carbon monoxide furnished chemo- and stereoselectively either bicyclic ketoesters 7 (from 1) and 15 (f
