DIASTEREOCONTROLLED NICKEL(O)- AND PALLADIUM(O) CATALYZED "METALLO-ENE-TYPE" CYCLIZATIONS/CARBONYLATIONS

DOI: 10.1016/S0040-4039(01)93496-3

Source and publish data:

Tetrahedron Letters p. 5883 - 5886 (1989)

Update date:2022-08-05

Topics:

Authors:

Oppolzer, Wolfgang

Keller, Thomas H.

Bedoya-Zurita, Manuel

Stone, Charles

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Article abstract of DOI:10.1016/S0040-4039(01)93496-3

Treatment of 1-iodo(acetoxy)-2,7-octadienes 1 and 1-iodo(acetoxy)-2-en-7-ynes 12 with Ni(COD)2/dppb (THF/MeOH) or Pd(dba)2/PPh3 (AcOH, then CH2N2) under carbon monoxide furnished chemo- and stereoselectively either bicyclic ketoesters 7 (from 1) and 15 (f

Full text of DOI:10.1016/S0040-4039(01)93496-3

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