127491-76-3Relevant academic research and scientific papers
Condensation of adamantanone with methylene-active compounds
Popov,Mokhov,Tankabekyan
, p. 404 - 409 (2013/07/04)
A convenient method was developed for the preparation of potentially bioactive substances with 2-adamantyl radical and of intermediates for their synthesis. Condensation of adamantanone with methylene-active compounds was performed, and the reaction features were determined.
A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6
Senthilvelan, Annamalai,Lee, Gene-Hsiang,Chung, Wen-Sheng
, p. 7179 - 7183 (2007/10/03)
The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.
Electronic and Steric Influences on Face Selection during the Oxy-Cope Rearrangement of an α-Allyl-α-vinylbenzyl Alcohol
Lin, Man-hua,Watson, William H.,Kashyap, Ram P.,Noble, W. J. le
, p. 3597 - 3602 (2007/10/02)
The racemic RR,SS and RS,SR diastereomers of 5-(5-fluoroadamant-2-ylidene)-4-hydroxy-4-phenyl-1-pentene (1-F) have been synthesized.Their configurations have been determined by means of 13C NMR as well as by way of an X-ray diffraction study of
