127752-94-7Relevant academic research and scientific papers
REACTIONS OF ORTHOFORMIC ESTER WITH MONOSUBSTITUTED AMIDE OXIMES
Andrianov, V. G.,Eremeev, A. V.
, p. 1402 - 1405 (2007/10/02)
In the reactions of N-monosubstituted p-nitrobenzamide oximes with orthoformic ester in presence of boron trifluoride ether complex p-nitrobenzonitrile and a carbamate of the original amide oxime are formed.Under the same condition bis(methylamino)glyoxime gives a 1-cyano-N-methylformamide oxime carbamate.
CONFIGURATION ON THE C=N DOUBLE BOND OF MONOSUBSTITUTED AMIDINES AND AMIDOXIMES
Tinant, Bernard,Dupont-Fenfau, Janine,Declercq, Jean-Paul,Podlaha, Jaroslav,Exner, Otto
, p. 3245 - 3252 (2007/10/02)
Configuration on the C=N double bond of amidines and amidoximes is controlled by steric effects on the second nitrogen atom but there is a difference in the case of N'-monosubstituted derivatives: amidines prefer E configuration (conformation around the C
