127787-71-7

Basic information

• Product Name: dimethyl <(4-bromophenyl)diphenylmethyl>phosphonate
• CAS NO: 127787-71-7
• Molecular Weight: 431.266
• Mol File: 127787-71-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl <(4-bromophenyl)diphenylmethyl>phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl <(4-bromophenyl)diphenylmethyl>phosphonate(127787-71-7)
• EPA Substance Registry System: dimethyl <(4-bromophenyl)diphenylmethyl>phosphonate(127787-71-7)

Safety Data

• Hazardous Substances Data: 127787-71-7(Hazardous Substances Data)

Upstream product

• 127787-74-0 p-bromophenyltrityl chloride 
• 121-45-9 phosphorous acid trimethyl ester 

Relevant articles and documents

Photolysis of triarylmethylphosphonic acids and their esters

Upon UV-irradiation in an alkaline alcohol solution, some triarylmethylphosphonic acids underwent C-P bond cleavage to give triarylmethanes and alkyl dihydrogenphosphates, while, in an acidic or a neutral alcohol solution, they afforded biaryls. Their dimethyl esters gave also biaryls and dimethyl [alkoxy(aryl)methyl]phosphonates, which were derived from the insertion of (dialkoxyphosphinyl) arylcarbenes into the OH bond of the alcohol. The carbene was generated by photo-α,α-elimination of two aryl groups of the phosphonate.