1279129-86-0Relevant academic research and scientific papers
BORON-CONTAINING PI-ELECTRON MATERIALS INCORPORATING FORMALLY AROMATIC AND NEUTRAL BOREPIN RINGS
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Page/Page column 76, (2011/10/31)
The synthesis, functionalization and characterization of borepin-based extended pi-electron molecules is disclosed. Bulky substituents shielded the vacant boron p-orbitals thus allowing synthetic manipulation and purification under ambient lab conditions.
Organic halogenation chemistry as a vital tool for the construction of functional π-conjugated materials
Tovar, John D.
scheme or table, p. 2387 - 2391 (2011/09/21)
Recent and ongoing efforts by the Tovar research group to exploit organic halogenation chemistry for the development of complex organic electronic materials are described. Standard synthetic approaches involving free-radical and electrophilic reaction pathways are presented along with strategies that use ionizable protons or triazenes as masking groups for aromatic halides. Forward synthetic processes that highlight the extended chemistry that can be applied to these halogenated substrates to give complex π-conjugated molecules are also discussed. The examples presented are specific to work from the groups laboratories, but the halogenation procedures are sufficiently general to be suitable for use on many other conjugated frameworks. Georg Thieme Verlag Stuttgart New York.
Functionalized dibenzoborepins as components of small molecule and polymeric π-conjugated electronic materials
Caruso, Anthony,Tovar, John D.
, p. 2227 - 2239 (2011/06/11)
We present the synthesis and characterization of dibenzo[b,f]borepins (DBBs) functionalized at the para and meta position with respect to the boron center in order to understand how regiochemical issues influence photophysical and electrochemical properti
