128081-29-8Relevant articles and documents
Direct use of 1,3-dienes for the allylation of ketones: Via catalytic hydroindation
Miyamoto, Shinji,Shibata, Ikuya,Suzuki, Itaru,Yagi, Kensuke
, p. 6030 - 6034 (2020)
In this study, in situ catalytically generated allylic indium from 1,3 dienes and InCl2H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C b
First preparation of allyl vanadium reagents in a mixed solvent of THF and HMPA (HMPA = hexamethylphosphoric triamide) and their application to allylation of carbonyl compounds
Kataoka, Yasutaka,Makihira, Isamu,Tani, Kazuhide
, p. 7083 - 7086 (2007/10/03)
Allylation of carbonyl compounds with allyl bromide mediated by a vanadium(II) complex in a mixed solvent of THF and HMPA (HMPA = hexamethylphosphoric triamide) has been accomplished. Coordination of HMPA to a vanadium metal is essential for the stabilization of the allyl vanadium species.