128316-23-4Relevant academic research and scientific papers
UV light-mediated difunctionalization of alkenes through aroyl radical addition/1,4-/1,2-Aryl shift cascade reactions
Zheng, Lewei,Huang, Hongli,Yang, Chao,Xia, Wujiong
supporting information, p. 1034 - 1037 (2015/03/30)
UV light-mediated difunctionalization of alkenes through an aroyl radical addition/1,4-/1,2-aryl shift has been described. The resulted aroyl radical from a photocleavage reaction added to acrylamide compounds followed by cyclization led to the formation of oxindoles, whereas the addition to cinnamic amides aroused a unique 1,4-aryl shift reaction. Furthermore, the difunctionalization of alkenes of prop-2-en-1-ols was also achieved through aroyl radical addition and a sequential 1,2-aryl shift cascade reaction.
FeCl2-catalyzed selective C-C bond formation by oxidative activation of a benzylic C-H bond
Li, Zhiping,Cao, Lin,Li, Chao-Jun
, p. 6505 - 6507 (2008/09/17)
(Chemical Equation Presented) Any old iron: Readily available and non-toxic FeCl2 effectively catalyzes C-C bond formation by oxidative activation of benzylic C-H bonds in the presence of tert-butyl peroxide as a stoichiometric oxidant (see sch
CHEMISTRY OF OXALYL DERIVATIVES OF METHYL KETONES XLVII. REACTION OF N-ARYLAROYLPYRUVAMIDES WITH DIPHENYLDIAZOMETHANE
Brigadnova, E. V.,Maslivets, A. M.,Andreichikov, Yu. S.
, p. 274 - 277 (2007/10/02)
N-Aryl-4-aryl-3-diphenylmethyl-2,4-dioxobutyramides were obtained from N-arylaroylpyruvamides and diphenyldiazomethane.At 110 deg C in toluene they were converted into N-aryl-3-aryl-2-diphenylmethyl-3-oxopropionamides.By boiling in acetic acid they were converted into 1,5-diaryl-4-diphenylmethyl-2,3-dihydro-2,3-pyrrolediones.
