1283735-33-0Relevant academic research and scientific papers
Syntheses and characterizations of two zinc(II) metal-organic frameworks based on 1,4-naphthalenedicarboxylate and imidazole ligands
Wang, Jingyuan,You, Hongpeng
, p. 415 - 420 (2011)
Two new compounds, namely [Zn(1,4-ndc)(L1)] (1), and [Zn(1,4-ndc)(L2)] ·0.25H2O (2) [L1 = 2-phenylimidazole, L2 = 1,1'-(1,4-butanediyl)bis(imidazole), and 1,4-ndc = 1,4-naphthalenedicarboxylate] were successfully synthesized under similar hydrothermal conditions. In compound 1, each 1,4-ndc anion links two neighboring ZnII cations with its carboxylate groups to generate a 2D layer structure. The L1 ligands are attached on both sides of the layers. In compound 2, each carboxylate group of 1,4-ndc connects one ZnII atom in monodentate mode to form a 1D zigzag chain. Further, the L2 ligands link the chains to generate an expanded diamond net. Four diamond networks interweave to form a 3D interpenetrating diamond framework in an unusual [2+2] mode. Furthermore, the title compounds exhibit good luminescent properties in the range from ultraviolet to visible light and may find potential applications as fluorescent materials. Copyright
