128461-94-9Relevant academic research and scientific papers
Stereocontrolled halofluorination of glycals with silicon tetrafluoride, leading to a facile synthesis of glycosyl fluorides
Shimizu, Makoto,Nakahara, Yuko,Yoshioka, Hirosuke
, p. 57 - 60 (2007/10/03)
Bromofluorination of glycals was carried out with SiF4, 1,3-dibromo-5,5-dimethylhydantoin (DBH), and H2O in 1,4-dioxane in the presence of HMPA to give bromofluoro sugars in good yields with good selectivities. Subsequent debrominati
Synthetic Study toward Vineomycins. Synthesis of C-Aryl Glycoside Sector via Cp2HfCl2-AgClO4-Promoted Tactics
Matsumoto, Takashi,Katsuki, Miyoko,Jona, Hideki,Suzuki, Keisuke
, p. 6185 - 6188 (2007/10/02)
Regio- and stereo-controlled formation of C-aryl β-D-olivoside linkage is achieved by the reaction of naphthol or anthrol derivatives with D-olivosyl fluoride.The reaction is efficiently promoted by Cp2HfCl2-AgClO4 and the bond formation occurs selectivit
