106988-66-3

Upstream product

• 32469-90-2 methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-ribohexopyranoside 
• 64429-65-8 methyl 3,4-di-O-benzoyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 32476-34-9 Methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 61198-84-3 1,3,4-Tri-O-benzoyl-2,6-didesoxy-ξ-L-ribo-hexopyranose 

Downstream Products

• 130780-27-7 C₃₀H₂₆O₆ 
• 130780-28-8 C₃₀H₂₆O₆ 
• 130780-25-5 C₂₂H₂₂O₇ 
• 128461-95-0 C₃₀H₂₆O₆ 
• 128461-96-1 C₃₀H₂₆O₆ 
• 128462-02-2 C₃₇H₃₄O₉ 
• 128462-00-0 C₃₁H₂₈O₇ 
• 128461-97-2 C₃₀H₂₆O₆ 
• 128461-94-9 3,4-di-O-benzoyl-2,6-dideoxy-α-D-arabinopyranosyl fluoride 
• 136459-89-7 acetyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 128461-95-0 C₃₀H₂₆O₆ 
• 130780-32-4 C₃₀H₂₆O₆ 
• 104652-08-6 methyl 4-O-(3,4-di-O-benzoyl-2,6-dideoxy-α-D-ribopyranosyl)-3-O-benzoyl-2,6-dideoxy-α-D-ribo-hexopyranoside 
• 104652-07-5 methyl 4-O-(3,4-di-O-benzoyl-2,6-dideoxy-β-D-ribopyranosyl)-3-O-benzoyl-2,6-dideoxy-α-D-ribo-hexopyranoside 

Relevant academic research and scientific papers

Improvement in O -> C Glycoside Rearrangement Approach to C-Aryl Glycosides: Use of 1-O-Acetyl Sugar as Stable but Efficient Glycosyl Donor

1-O-Acetyl sugars serve as efficient glycosyl donor in the O -> C-glycoside rearrangement approach to C-aryl glycosides.Model study was carried out on three types of 2-deoxy-glycosyl acetates including amino sugar derivative.Comparison of the promoters, Cp2HfCl2-AgClO4, SnCl4, BF3*OEt2 is described.

Synthetic Study toward Vineomycins. Synthesis of C-Aryl Glycoside Sector via Cp2HfCl2-AgClO4-Promoted Tactics

Regio- and stereo-controlled formation of C-aryl β-D-olivoside linkage is achieved by the reaction of naphthol or anthrol derivatives with D-olivosyl fluoride.The reaction is efficiently promoted by Cp2HfCl2-AgClO4 and the bond formation occurs selectivit

Syntheses of Selectively Alkylated Enol Ethers in the L-ribo Series

The reduction of enulose 1a predominantly leads to L-digitoxal (3a), although this method presents a sluggish reaction with moderate yields.In contrast, the preparation from L-digitoxose (4a) in a three-step one-pot procedure represents an advantageous approach.Regioselective 3- or 4-O-alkylations are achieved by phase-transfer catalysis method or via stannylidene intermediates to give monosaccharide precursors of the L-ribo series valuable for further interglycosidic linking.