1286189-69-2Relevant academic research and scientific papers
Bis(cycloocta-1,5-diene)nickel-Catalyzed Carbon Dioxide Fixation for the Stereoselective Synthesis of 3-Alkylidene-2-indolinones
Miao, Bukeyan,Zheng, Yangguangyan,Wu, Penglin,Li, Suhua,Ma, Shengming
, p. 1691 - 1707 (2017/05/22)
A bis(cycloocta-1,5-diene)nickel-catalyzed highly regio- and (E)-stereoselective hydrocarboxylation of 2-alkynylanilines under very mild conditions has been developed to afford (E)-[2-(o-aminophenyl)]acrylic acids, which could easily be converted to (E)-3
Highly regio- and stereoselective three-component nickel-catalyzed syn-hydrocarboxylation of alkynes with diethyl zinc and carbon dioxide
Li, Suhua,Yuan, Weiming,Ma, Shengming
supporting information; experimental part, p. 2578 - 2582 (2011/05/03)
Hydrocarboxylation of alkynes: The first example of nickel-catalyzed hydrozincation of alkynes that form stereodefined hydrocarboxylation products is presented (see scheme; cod=cycloocta-1,5-diene). This catalytic system is efficient for the activation of CO2 and the three-component reaction produces products that could be converted into important oxindole or γ-butyrolactam derivatives. Copyright
