1286793-40-5

Upstream product

• 67-56-1 methanol 
• 13633-26-6 4-phenylbut-1-en-3-yne 
• 73183-34-3 bis(pinacol)diborane 
• 459126-04-6 diethyl (3-phenylprop-2-yn-1-yl) phosphate 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 

Relevant academic research and scientific papers

Copper-catalyzed propargylation of diborylmethane

A Cu/PPh3-catalyzed propargylic substitution reaction of diborylmethane is reported. Different substituted propargyl electrophiles can be employed in this reaction, and various synthetic valuable functional groups can be tolerated. Di-deuterate

Copper(i)-catalyzed regioselective monoborylation of 1,3-enynes with an internal triple bond: Selective synthesis of 1,3-dienylboronates and 3-alkynylboronates

Hooray for hydroboration! The products afforded by the title reaction depend on the substitution pattern on the double bond moiety of 1,3-enyne substrates (see scheme). These types of products, either 1,3-dienylboronates or 3-alkynylboronates, are difficult to obtain by other methods. Interestingly, ligand-controlled borylation was observed with high selectivity in some cases. pin=pinacolato, THF=tetrahydrofuran. Copyright