128700-57-2Relevant academic research and scientific papers
Highly stereoselective carbon-carbon bond-forming reactions on cyclopropane rings using 1-(methoxycarbonyl)cyclopropylzinc bromides
Sakuma, Daichi,Yamada, Kenta,Sasazawa, Kazuya,Nishii, Yoshinori
, p. 818 - 820 (2015)
Highly stereoselective Reformatsky reaction and Pd-catalyzed arylation using 1-(alkoxycarbonyl)cyclopropylzinc bromide proceeded to give the trans-adduct as the major product in good to high yields with good to excellent stereoselectivities.
Electrophile-induced C-C bond activation of vinylcyclopropanes for the synthesis of Z -alkylidenetetrahydrofurans
Ganesh, Venkataraman,Kundu, Taraknath,Chandrasekaran, Srinivasan
, p. 380 - 399 (2013/03/28)
We present a detailed study on the behavior of vinylcyclopropanes as masked donor-acceptor system toward the stereoselective synthesis of Z-alkylidenetetrahydrofurans. Results of bromenium catalyzed indirect activation of C-C bond of vinylcyclopropanes an
Enhancement of cyclopropanation chemistry in the silver-catalyzed reactions of aryldiazoacetates
Thompson, Janelle L.,Davies, Huw M. L.
, p. 6090 - 6091 (2008/02/07)
AgSbF6 is an effective catalyst for the reactions of donor/acceptor substituted carbenoids and shows a very different reactivity profile from the traditional rhodium-catalyzed reactions. Most notably, cyclopropanation of sterically hindered alk
STEREOSELECTIVE CYCLOPROPANATIONS WITH VINYL CARBENOIDS
Davies, Huw M. L.,Clark, T. Jeffrey,Church, Linda A.
, p. 5057 - 5060 (2007/10/02)
Rhodium(II) acetate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes results in cyclopropanation with a high degree of stereoselectivity.
