1287718-22-2

Upstream product

• 3282-30-2 pivaloyl chloride 
• 65854-91-3 N-(4-chlorophenyl)-2,2-dimethylpropionamide 
• 1313017-14-9 N-[4-chloro-2-(2,2-dimethyl-1-oxopropyl)phenyl]-N,2,2-trimethylpropanamide 
• 1287718-07-3 1-[5-chloro-2-(methylamino)phenyl]-2,2-dimethyl-1-propanone 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 
• 1313017-13-8 N-[4-chloro-2-(2,2-dimethyl-1-oxopropyl)phenyl]-2,2-dimethylpropanamide 

Downstream Products

• 1287718-39-1 (R(S))-N-(S)-[1-[5-chloro-2-(methylamino)phenyl]-2,2-dimethylpropyl]-2-methyl-2-propanesulfinamide 
• 1313023-38-9 (R(S))-N-(S)-[1-[5-chloro-2-(dimethylamino)phenyl]-2,2-dimethylpropyl]-2-methyl-2-propanesulfinamide 
• 1287718-67-5 (R(S))-2-((1S)-1-[tert-butyl(methyl)oxo-λ6-sulfanylidene]amino-2,2-dimethylpropyl)-4-chloro-N-methylaniline 
• 1287838-43-0 (1S)-1-[5-chloro-2-(methylamino)phenyl]-2,2-dimethyl-1-propanamine 
• 1287838-44-1 (1S)-1-[5-chloro-2-(dimethylamino)phenyl]-2,2-dimethyl-1-propanamine 
• 1287838-46-3 (1S)-1-[5-chloro-2-(methylamino)phenyl]-N,2,2-trimethyl-1-propanamine 
• 1287838-47-4 (1S)-1-[5-chloro-2-(dimethylamino)phenyl]-N,2,2-trimethyl-1-propanamine 
• 1287718-78-8 (1S)-1-[5-chloro-2-(dimethylamino)phenyl]-N,2,2-trimethyl-1-propanamine hydrochloride 
• 1313022-62-6 N-[(Z)-1-[5-chloro-2-(dimethylamino)phenyl]-2,2-dimethylpropylidene]-2-methyl-(R(S))-2-propanesulfinamide 

Relevant academic research and scientific papers

Asymmetric synthesis of 1,3-diamines. II: Diastereoselective reduction of atropisomeric N-tert -butanesulfinylketimines

Chiral, nonracemic o-aminobenzylamines were prepared in a highly diastereoselective reduction of atropisomeric N-tert-butanesulfinylketimines. The ortho-substituent ensures the distinct reactivity of atropisomers 4d-f. The free energy of activation for at